Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex
نویسندگان
چکیده
A pentacoordinate methylidene carbon atom was trapped in a neutral trimetallic aluminum core using naphthalene bis amidinate ligand. The resulting complex exhibits the shortest equatorial Al–C bond distance reported for Al 3 -(μ -CH 2 ) moieties.
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2021
ISSN: ['1359-7345', '1364-548X']
DOI: https://doi.org/10.1039/d1cc04265c